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Ag(III)···Ag(III) Argentophilic Interaction in a Cofacial Corrole Dyad

https://doi.org/10.1021/acs.inorgchem.2c02285

Lemon, Christopher M. ; Powers, David C. ; Huynh, Michael ; Maher, Andrew G. ; Phillips, Austin A. ; Tripet, Brian P. ; Nocera, Daniel G. ( January 2023 , Inorganic Chemistry)

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Solvent-Induced Spin-State Change in Copper Corroles

https://doi.org/10.1021/acs.inorgchem.2c02678

Lemon, Christopher M. ; Maher, Andrew G. ; Anderson, Bryce L. ; Bloch, Eric D. ; Huynh, Michael ; McCollar, Abie L. ; Nocera, Daniel G. ( December 2022 , Inorganic Chemistry)

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Multielectron C–H photoactivation with an Sb( v ) oxo corrole

https://doi.org/10.1039/c9cc09892e

Lemon, Christopher M. ; Maher, Andrew G. ; Mazzotti, Anthony R. ; Powers, David C. ; Gonzalez, Miguel I. ; Nocera, Daniel G. ( May 2020 , Chemical Communications)

Pnictogen complexes are ideal for mediating multi-electron chemical reactions in two-electron steps. We report an Sb( v ) bis-μ-oxo corrole that photochemically oxidises the C–H bonds of organic substrates. In the case of toluene, the substrate is oxidised to benzaldehyde, a rare example of a four-electron photoreaction.
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